Good choice is Nikkor 10-24 (some refer it to be even tack sharper then Nikkor 12-24 DX). The ultimate lens is Nikkor 14-24/2,8 - probably best UWA zoom. To get pretty sharp results keep f6,3-9 - you can test each lens for the best aperture (some at f7, some at f9 etc.) but the difference between f6,3 and f9 is usually very small and most lenses deliver good results.
Sigma 10-20 isnt the sharpest lens and you cant expect it to be as sharp as macro lens like Tamron 90. The other thing is that Sigma lenses usually have pretty different quality piece to piece = you better go into the shop and try 3-4 pieces and choose the best one. Buying Sigma from eshop = hit or miss.
RAW is usually visibly less sharp then JPEG - RAWs are not so heavily processed with firmware, all agencies say not to sharpen your pictures but if you dont, they will reject it. I usually need to push contrast and sharpness while processing RAW to get proper results. My acceptance is aprox. 80% across big 4 = seems it works pretty good